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1 article(s) from Schiffels, Johannes

Olefin metathesis catalysts embedded in β-barrel proteins: creating artificial metalloproteins for olefin metathesis

Daniel F. Sauer,
Johannes Schiffels,
Takashi Hayashi,
Ulrich Schwaneberg and
Jun Okuda

Beilstein J. Org. Chem. 2018, 14, 2861–2871, doi:10.3762/bjoc.14.265

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Graphical Abstract

Scheme 1: Left: Mechanism of the olefin metathesis reaction postulated by Chauvin [2]. Right: Potential influenc...

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Scheme 2: (i) Ring-opening metathesis polymerization (ROMP), (ii) ring-closing metathesis (RCM) and (iii) cro...

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Figure 1: Common anchoring strategies for metal-complex or metal ion incorporation into protein scaffolds.

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Scheme 3: Biotinylated GH-type catalysts for conjugation to (strept)avidin and their catalyzed ring-closing m...

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Scheme 4: Whole-cell artificial metatheases designed by Ward et al. [47].

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Scheme 5: Coupling of GH-type catalysts Ru-4/5/6 to NB4 or NB11.

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Scheme 6: Anchoring and refolding of GH-type catalysts Ru-4/5/6 to FhuA.

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Figure 2: Top: NB4 (PDB 3WJB); bottom: NB4exp. Highlighted in blue are the additional two β-sheets. Highlight...

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Review

Published 19 Nov 2018

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